I may have worded things incorrectly before-hand, I'm kind of tired.
Anyways, Krillen is placing emphasis on Goku's prediction and how Gotenks should definitely win no matter what, as opposed to the amount of Chi that he sensed from Gotenks.
There is no sure statement that Gotenks lived up to the expectations Goku had for him, and it is kind of illogical for someone to say that he had. Additionally, Super Boo's initial battle power - the battle power that he arrived on Korin's tower with, is implied to be the same as Innocent Boo's. Hence why Piccolo has to inform Krillen that Gotenks stands no chance, and he has to tell the boys that more then just his appearance has changed. Just because his battle power is the same as it was before doesn't necessarily mean that he is actually the same Boo from before.
Goku also noticed a change in Majin Boo's Chi, so it implied that he was sensing something all along. Even if you wish to disregard that, Goku was continuously sensing the events on Earth -and even at one time, he wished that he had some way of actually seeing these events; hence the introduction of Elder Kaioshins crystal ball. So it isn't surprising that he caught onto Super Boo's power-burst.
Everyone on Korin's tower except Piccolo and Dende were acting rather casual. Krillen was walking around without a care in the world, Goten and Trunks were sleeping, et cetera. It's no wonder they didn't catch on.